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Are there any good natural pesticides that will keep harmful bugs away from plants while keeping them safe for animals/people?
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Yes, plenty, and here is one for you as you can mix it up now and it will prevent most insects from approaching any of your plants:

1 Gallon of lukewarm water, mix with 4 ounces of concentrated lime juice, and 1 ounce of white vinegar

Now spray over the plants that you want to protect, the lime interacts with the vinegar, insects do not enjoy the mixture because it interferes with the intake of air, it inhibits most major organs, so they avoid the area like a plague, this, however, does no harm to beetles.
I don't like to use chemicals on my plants and have found some good home remedies in this article.

https://lifeindirt.com/5-home-remedies-for-what-is-wrong-with-my-plant

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